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1 article(s) from Ragains, Justin R

Application of visible-light photosensitization to form alkyl-radical-derived thin films on gold

Rashanique D. Quarels,
Xianglin Zhai,
Neepa Kuruppu,
Jenny K. Hedlund,
Ashley A. Ellsworth,
Amy V. Walker,
Jayne C. Garno and
Justin R. Ragains

Beilstein J. Nanotechnol. 2017, 8, 1863–1877, doi:10.3762/bjnano.8.187

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Scheme 1: Proposed visible-light-promoted thin film deposition on Au surface.

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Scheme 2: Phthalimide esters used for the deposition of thin films.

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Figure 1: Nanopores within a film of Au–Me on Au(111) produced using immersion particle lithography and the r...

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Figure 2: Attempted nanoshaving of the Au–Me Film on Au (111). (a) Topography image of nanopores within the f...

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Figure 3: Au–Me thin film prepared in the absence of Ru(bpy)₃Cl₂ was not robust. (a) Topography image of nano...

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Figure 4: Film of Au–NHBoc prepared on Au(111) with nanopores using particle lithography. (a) Topograph of na...

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Figure 5: Au–NHBoc film after storage in ambient conditions for six months. (a) Topography image; (b) zoom-in...

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Figure 6: IRRAS Spectrum of Au–Me.

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Figure 7: IRRAS Spectrum of Au–NHBoc.

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Figure 8: Au 4f, C 1s and O 1s photoelectron spectra of the deposited Au–Me layer.

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Figure 9: a) Positive ion mass spectrum m/z 40–75 and b) negative ion mass spectrum m/z 190–290 of the deposi...

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Scheme 3: A mechanistic hypothesis for multilayer formation, crosslinking, and alkene formation.

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Published 06 Sep 2017

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